Abstract: The reaction of 1-((1H-imidazol-4-yl)methylene)thiosemicarbazide (HL) with NiCl2.6H2O in 2:1 ratio has yielded a mononuclear formulated as [Ni(HL)2].2Cl. The structure of the complex was solved by single crystal X–ray crystallography. The asymmetric unit of the mononuclear complex is composed by one Ni2+ ion, two neutral molecules of ligand and two chloride anions. Each ligand molecule acts in tridentate fashion yielding a hexacoordinated Ni(II) ion with an environment best described.......
Key words: Schiff base, crystal, complex, copper, octahedral, mononuclear
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